Product ID:CLC-700/800 TONER BLACK, F42-0401-100
MSDS Date:02/01/1994
FSC:6850
NIIN:00N063315
MSDS Number: BYVPW

CANON USA INC

ONE CANON PLAZA
LAKE SUCCESS, NY 11042
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 516-328-5600

Preparer: JOSEPH PALMERI

Cage: 1BA63

CANON USA INC

LAKE SUCCESS, NY 11042 US

Telephone: 516-328-5600

Cage: 1BA63

BISPHENOL A PROPYLENE OXIDE FUMARATE; (POLYESTER RESIN)

CAS: 39382-25-7

Fraction By Weight: 85-95%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 3-10%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

CHROMIUM (III) AND COMPOUNDS (1% AS CHROMIUM (III) METAL)

CAS: 16065-83-1

RTECS: GB6261000

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50: (ORAL, RAT) >5000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL/SKIN: EXPECTED TO BE LOW HAZ FOR
RECOM HNDLG. NOT CLASSIFIED AS SKIN IRRIT ACCDG TO OSHA STDS. EYE:
NO SPECIFIED HAZS KNOWN. MAY CAUSE TRANSIENT IRRIT. NOT CLASSIFIED
AS IRRIT ACCDG TO OSHA STDS . INGEST: EXPECTED TO BE LOW INGEST
HAZ. CHRONIC: BASED UPON AVAIL DATA, HUMAN EXPOS TO TONER HAS BEEN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SHOWN TO CAUSE MINIMAL RESP TRACT
IRRIT AS MAY OCCUR W/LG AMTS OF ANY NONTOX DUSTS. RSLTS OF ONE
ANIMAL STUDY WHERE RATS INHALED TONER THAT WAS 10 TIMES MORE
RESPIRABLE THAN COMMERCIALLY AVA IL TONER WERE OBSERVED TO HAVE NO
LUNG CHANGES AT LOW EXPOS (MOST RELEVANT LEVEL TO POTNTL HUMAN
EXPOS). AT (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS EYE
SHOULD BE WASHED OUT IMMEDIATELY WITH WATER FOR AT LEAST 15
MINUTES. GET MEDIC AL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGEST:
DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CEHMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES. HAZARDOUS COMBUSTION PRODUCTS: CARBON DIOXIDE,
CARBON MONOXIDE.

Spill Release Procedures:SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER
CARTON.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP FROM CNTCT W/OXIDIZING MATLS.
MINIMIZE DUST GENERATION & ACCUMULATION. REFER TO PAMPHLET #654,
"PREVENTION OF FIRE & DUST EXPLOSIONS IN (SUPDAT)
Other Precautions:AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION.
WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED. USE NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GOOD VENTILATION (TYPICALLY 4-6 ROOM VOLUMES PER HR) SHOULD
BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH FOUNTAIN &
DELUGE SHOWER .
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRAC SHOULD BE FOLLOWED
WHICH INCLS PREVENTING EYE CONTACT, MINIMIZING SKIN CONTACT,
INHALATION.
Supplemental Safety and Health
EFTS OF OVEREXP: HIGHER LEVELS A SLIGHT DEGREE OF LUNG FIBROSIS WAS
OBSERVED DUE TO EXCESSIVE AMTS OF DUST RETAINED IN LUNGS FOR A
PROLONGED INTERVAL. HNDLG/STOR PRECS: THE CHEMICAL, DYE,
PHARMACEUTIC AL AND PLASTICS INDUSTRIES." USE ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.

Melt/Freeze Pt:M.P/F.P Text:>212F,>100C
Spec Gravity:1.0-1.2(H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK SOLID POWDER; SLIGHT PLASTIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE
AND POSSIBLY TOXIC CHEMICALS SUCH AS CARBON MONOXIDE OR OXIDES OF
NITROGEN.

Waste Disposal Methods:INCINERATE OR LANDFILL. CAN BE INCINERATED WHEN
IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. DISCHARGE,
TREATMENT OR DISPOSAL ARE SUBJECT TO FEDERAL, STATE AND LOCAL LAWS.
EMPTY RECEPTACLE MAY BE RECYCLED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.